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51.
Lens-less Fourier-transform holography has been actively studied because of its simple optical structure and its single-shot recording.However,a low-contrast interferogram between the reference and object waves limits its signal to noise ratio.Here,multi-reference lens-less Fourier-transform holography with a Greek-ladder sieve array is proposed in the experiment and demonstrated effectively to improve the signal to noise ratio.The key technique in our proposed method is a Greek-ladder sieve array,which acts as not only a wave-front modulator but also a beam splitter.With advantages of the common path,single shot,and no need for a lens,this system has enormous potential in imaging and especially in extreme ultraviolet and soft X-ray holography. 相似文献
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Pingyu Zhu Qilin Zheng Shichuan Xue Chao Wu Xinyao Yu Yang Wang Yingwen Liu Xiaogang Qiang Junjie Wu Ping Xu 《Frontiers of Physics》2020,15(6):61501
One of the most important multipartite entangled states, Greenberger–Horne–Zeilinger state (GHZ), serves as a fundamental resource for quantum foundation test, quantum communication and quantum computation. To increase the number of entangled particles, significant experimental efforts should been invested due to the complexity of optical setup and the difficulty in maintaining the coherence condition for high-fidelity GHZ state. Here, we propose an ultra-integrated scalable on-chip GHZ state generation scheme based on frequency combs. By designing several microrings pumped by different lasers, multiple partially overlapped quantum frequency combs are generated to supply as the basis for on-chip polarization-encoded GHZ state with each qubit occupying a certain spectral mode. Both even and odd numbers of GHZ states can be engineered with constant small number of integrated components and easily scaled up on the same chip by only adjusting one of the pump wavelengths. In addition, we give the on-chip design of projection measurement for characterizing GHZ states and show the reconfigurability of the state. Our proposal is rather simple and feasible within the existing fabrication technologies and we believe it will boost the development of multiphoton technologies. 相似文献
54.
Selective extraction of catecholamines by packed fiber solid‐phase using composite nanofibers composing of polymeric crown ether with polystyrene 下载免费PDF全文
Li‐Qin Chen Yu Wang Jian‐Song Qu Jian‐Jun Deng Xue‐Jun Kang 《Biomedical chromatography : BMC》2015,29(1):103-109
For the first time, electrospun composite nanofibers comprising polymeric crown ether with polystyrene (PCE‐PS) have been used for the selective extraction of catecholamines – dopamine (DA), norepinephrine (NE) and epinephrine (E) – prior to their analysis by high‐performance liquid chromatography–electrochemical detection. Using a minicartridge packed with PCE‐PS composite nanofibers, the target compounds were extracted effectively from urine samples to which diphenylborinic acid 2‐aminoethyl ester was added as a complexing reagent. The extracted catecholamines could be liberated from the fiber by the addition of acetic acid. A good linearity was observed for catecholamines in the range of 2.0–200 ng mL?1 (NE, E and DA). The detection limits of catecholamines (signal‐to‐noise ratio = 3) were 0.5 ng mL?1 (NE), 0.2 ng mL?1 (E) and 0.2 ng mL?1 (DA), respectively. Under the optimized conditions, the absolute recoveries of the above three catecholamines were 90.6% (NE), 88.5% (E) and 94.5% (DA). The repeatability of extraction performance was from 5.4 to 9.2% (expressed as relative standard deviation). Our results indicate that the proposed method could be used for the determination of NE, E and DA in urine. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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Elastic,dielectric, and piezoelectric characterization of 0.92Pb(Zn1/3Nb2/3)O3-0.08PbTiO3 single crystal by Brillouin scattering 下载免费PDF全文
In this paper,a complete set of elastic,piezoelectric,and dielectric constants of high-quality tetragonal poled0.92Pb(Zn_(1/3)Nb_(2/3))O_3-0.08PbTiO_3 single crystal grown by the modified flux method is determined using high-resolution Brillouin scattering.A comparison is made between the results obtained by a hybrid method combining ultrasonic and resonant techniques and the results obtained by the Brillouin scattering.The elastic,piezoelectric,and dielectric constants obtained by the two methods are similar.The Brillouin spectrum consists of one longitudinal and two transverse acoustic phonon modes,and the variations of the Brillouin shifts,the full widths at half maximum,and the scattering intensities of these modes with scattering angle 9 are investigated.In particular,the transverse acoustic phonon mode at the lowfrequency becomes markedly soft from 28.2 GHz to 18.4 GHz and broadens gradually with the increase of θ,while its intensity decreases gradually as compared with that of the original one.The possible origins of the results are discussed. 相似文献
57.
Interplay of Hole Transfer and Host–Guest Interaction in a Molecular Dyad and Triad: Ensemble and Single‐Molecule Spectroscopy and Sensing Applications 下载免费PDF全文
Dr. Xiangyang Wu Dr. Fang Liu Dr. Kym L. Wells Serena L. J. Tan Prof. Dr. Richard D. Webster Prof. Dr. Howe‐Siang Tan Prof. Dr. Dawei Zhang Prof. Dr. Bengang Xing Prof. Dr. Edwin K. L. Yeow 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(8):3387-3398
A new molecular dyad consisting of a Cy5 chromophore and ferrocene (Fc) and a triad consisting of Cy5, Fc, and β‐cyclodextrin (CD) are synthesized and their photophysical properties investigated at both the ensemble and single‐molecule levels. Hole transfer efficiency from Cy5 to Fc in the dyad is reduced upon addition of CD. This is due to an increase in the Cy5‐Fc separation (r) when the Fc is encapsulated in the macrocyclic host. On the other hand, the triad adopts either a Fc‐CD inclusion complex conformation in which hole transfer quenching of the Cy5 by Fc is minimal or a quasi‐static conformation with short r and rapid charge transfer. Single‐molecule fluorescence measurements reveal that r is lengthened when the triad molecules are deposited on a glass substrate. By combining intramolecular charge transfer and competitive supramolecular interaction, the triad acts as an efficient chemical sensor to detect different bioactive analytes such as amantadine hydrochloride and sodium lithocholate in aqueous solution and synthetic urine. 相似文献
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An efficient and practical route to β‐keto sulfones has been developed through heterogeneous oxidative coupling of oxime acetates with sodium sulfinates by using an MCM‐41‐supported Schiff base‐pyridine bidentate copper (II) complex [MCM‐41‐Sb,Py‐Cu (OAc)2] as the catalyst and oxime acetates as an internal oxidant, followed by hydrolysis. The reaction generates a variety of β‐keto sulfones in good to excellent yields. This new heterogeneous copper (II) catalyst can be easily prepared via a simple procedure from readily available and inexpensive reagents and exhibits the same catalytic activity as Cu (OAc)2. MCM‐41‐Sb,Py‐Cu (OAc)2 is also easy to recover and is recyclable up to eight times with almost consistent activity. 相似文献
60.
Yaping Chen Dr. Kun Rui Prof. Jixin Zhu Prof. Shi Xue Dou Dr. Wenping Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):703-713
Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed. 相似文献